4. Raul – Spain
Euro qualifier goals scored: 18
Notching as many as Koller did, the Real Madrid legend is unlucky as he missed out on Spain’s golden generation and made his final appearance for the side in 2006 – two years before they picked up the first of their back-to-back European Championship titles. Still, with 18 of his 44 goals for La Rioja coming in helping them get to the tournament, he boasts a scoring record that nobody has been able to touch since.
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